4.2 Crystallization of Magma
The minerals that make up igneous rocks crystallize at a range of different temperatures. This explains why a cooling magma can have some crystals within it and yet remain predominantly liquid. The sequence in which minerals crystallize from a magma is known as the Bowen Reaction Series (Figures 4.2.1 and 4.2.2).
Of the common silicate minerals, olivine normally crystallizes first, at between 1200° and 1300°C. As the temperature drops, and assuming that some silica remains in the magma, the olivine crystals will react (combine) with some of the silica in the magma to form pyroxene. As long as there is silica remaining and the rate of cooling is slow, this process continues down the discontinuous branch: olivine to pyroxene, pyroxene to amphibole, and (under the right conditions) amphibole to biotite.
At about the point where pyroxene begins to crystallize, plagioclase feldspar also begins to crystallize. At that temperature, the plagioclase is calcium-rich (anorthite) (see Figure 3.1.6). As the temperature drops, and providing that there is sodium left in the magma, the plagioclase that forms is a more sodium-rich variety (e.g., albite).
Finally, if the magma is quite silica-rich to begin with, there will still be some left at around 750° to 800°C, and from this last magma, potassium feldspar, quartz, and maybe muscovite will form.
Figure 4.2.1: The Bowen reaction series describes the process of magma crystallization.
Norman Levi Bowen, born in Kingston, Ontario, studied geology at Queen’s University and then at MIT in Boston. In 1912, he joined the Carnegie Institution in Washington, D.C., where he carried out groundbreaking experimental research into the processes of cooling magmas. Working mostly with basaltic magmas, he determined the order of crystallization of minerals as the temperature drops. The method, in brief, was to melt the rock to a magma in a specially-made kiln, allow it to cool slowly to a specific temperature (allowing some minerals to form), and then quench it (cool it quickly) so that no new minerals form (only glass). The results were studied under the microscope and by chemical analysis. This was done over and over, each time allowing the magma to cool to a lower temperature before quenching.
The Bowen reaction series is one of the results of his work, and even a century later, it is an important basis for our understanding of igneous rocks. The word reaction is critical. In the discontinuous branch, olivine is typically the first mineral to form (at just below 1300°C). As the temperature continues to drop, olivine becomes unstable while pyroxene becomes stable. The early-forming olivine crystals react with silica in the remaining liquid magma and are converted into pyroxene, something like this:
Mg2SiO4 (olivine) + SiO2 becomes 2MgSiO3 (pyroxene)
This continues down the chain, as long as there is still silica left in the liquid.
The composition of the original magma is critical to magma crystallization because it determines how far the reaction process can continue before all of the silica is used up. The compositions of typical mafic, intermediate, and felsic magmas are shown in Figure 4.2.3. Note that, unlike Figure 4.1.1, these compositions are expressed in terms of “oxides” (e.g., Al2O3 rather than just Al). There are two reasons for this: one is that in the early analytical procedures, the results were always expressed that way, and the other is that all of these elements combine readily with oxygen to form oxides.
Figure 4.2.3: The chemical compositions of typical mafic, intermediate, and felsic magmas and the types of rocks that form from them.
Mafic magmas have 45% to 55% SiO2, about 25% total of FeO and MgO plus CaO, and about 5% Na2O + K2O. Felsic magmas, on the other hand, have much more SiO2 (65% to 75%) and Na2O + K2O (around 10%) and much less FeO and MgO plus CaO (about 5%).
The proportions of the main chemical components of felsic, intermediate, and mafic magmas are listed in the table below. (The values are similar to those shown in Figure 4.2.3)
|SiO2||65% to 75%||55% to 65%||45% to 55%|
|Al2O3||12% to 16%||14% to 18%||14% to 18%|
|FeO||2% to 4%||4% to 8%||8% to 12%|
|CaO||1% to 4%||4% to 7%||7% to 11%|
|MgO||0% to 3%||2% to 6%||5% to 9%|
|Na2O||2% to 6%||3% to 7%||1% to 3%|
|K2O||3% to 5%||2% to 4%||0.5% to 3%|
Chemical data for four rock samples are shown in the following table. Compare these with those in the table above to determine whether each of these samples is felsic, intermediate, or mafic.
As a mafic magma starts to cool, some of the silica combines with iron and magnesium to make olivine. As it cools further, much of the remaining silica goes into calcium-rich plagioclase, and any silica left may be used to convert some of the olivine to pyroxene. Soon after that, all of the magma is used up and no further changes takes place. The minerals present will be olivine, pyroxene, and calcium-rich plagioclase. If the magma cools slowly underground, the product will be gabbro; if it cools quickly at the surface, the product will be basalt (Figure 4.2.4).
Felsic magmas tend to be cooler than mafic magmas when crystallization begins (because they don’t have to be as hot to remain liquid), and so they may start out crystallizing pyroxene (not olivine) and plagioclase. As cooling continues, the various reactions on the discontinuous branch will proceed because silica is abundant, the plagioclase will become increasingly sodium-rich, and eventually potassium feldspar and quartz will form. Commonly even very felsic rocks will not have biotite or muscovite because they may not have enough aluminum or enough hydrogen to make the OH complexes that are necessary for mica minerals. Typical felsic rocks are granite and rhyolite (Figure 4.2.4).
Figure 4.2.4: Examples of the igneous rocks that form from mafic, intermediate, and felsic magmas.
The cooling behaviour of intermediate magmas lie somewhere between those of mafic and felsic magmas. Typical mafic rocks are gabbro (intrusive) and basalt (extrusive). Typical intermediate rocks are diorite and andesite. Typical felsic rocks are granite and rhyolite (Figure 4.2.4).
An igneous rock with large crystals, called phenocrysts, embedded in a groundmass of much finer crystals is indicative of a two-stage cooling process, and the texture is porphyritic (Figure 4.2.5). For the rock to be called “porphyritic” there has to be a significant difference in crystal size, where the larger crystals are at least 10 times larger than the average size of the smaller crystals.
Figure 4.2.5: Porphyritic textures, left: 1.3 cm long amphibole crystals in an intrusive igneous rock in which most of the crystals are less than 1 mm, right: 1 to 2 mm long feldspar crystals and 1 mm long amphibole crystals in a volcanic rock where most of the crystals are less than 0.1 mm.
As a magma cools below 1300°C, minerals start to crystallize within it. If that magma is then involved in a volcanic eruption, the rest of the liquid will cool quickly to form a porphyritic texture. The rock will have some relatively large crystals (phenocrysts) of the minerals that crystallized early, and the rest will be very fine grained or even glassy. Using Figure 4.2.6, predict what phenocrysts might be present where the magma cooled as far as line a in one case, and line b in another.
See more: 2-Butanone Density G/Ml
Figure 4.2.6: Bowen reaction series. Line a – at high temperature – intersects olivine, Line b – at a lower temperature – intersects pyroxene and amphibole on the left, and plagioclase feldspar on the right
See Appendix 2 for Practice Exercise 4.2 answers.